(-)-Spiroviolene

A spirocyclic diterpene with formula C20H32 which is produced by a diterpene cyclase gene expressed in an engineered Streptomyces host." []

ID EC Number Name
KEGG:R11823 4.2.3.158 geranylgeranyl-diphosphate diphosphate-lyase [cyclizing, (-)-spiroviolene-forming]
Rhea:RHEA:53621 4.2.3.158 (2E,6E,10E)-geranylgeranyl diphosphate => (−)-spiroviolene + diphosphate
Rhea:RHEA:53622 4.2.3.158 (−)-spiroviolene + diphosphate => (2E,6E,10E)-geranylgeranyl diphosphate
Rhea:RHEA:53623 4.2.3.158 (2E,6E,10E)-geranylgeranyl diphosphate <=> (−)-spiroviolene + diphosphate
BioCyc:RXN-18785 4.2.3.158 GERANYLGERANYL-PP --> CPD-20077 + PPI
Rhea:RHEA:53620 [53620] (2E,6E,10E)-geranylgeranyl diphosphate = (-)-spiroviolene + diphosphate