(-)-α-Pinene
alpha-Pinene (CAS: 80-56-8) is an organic compound of the terpene class and is one of two isomers of pinene. It is found in the oils of many species of many coniferous trees, notably the pine. It is also found in the essential oil of rosemary (Rosmarinus officinalis). Both enantiomers are known in nature. 1S,5S- or (-)-alpha-pinene is more common in European pines, whereas the 1R,5R- or (+)-alpha-isomer is more common in North America. The racemic mixture is present in some oils such as eucalyptus oil (Wikipedia). (-)-alpha-Pinene is found in almond.
| ID | EC Number | Name |
|---|---|---|
| KEGG:R05765 | 4.2.3.119 | geranyl-diphosphate diphosphate-lyase [cyclizing, (-)-alpha-pinene-forming] |
| Rhea:RHEA:25489 | 4.2.3.119 | (2E)-geranyl diphosphate => (1S,5S)-α-pinene + diphosphate |
| Rhea:RHEA:25490 | 4.2.3.119 | (1S,5S)-α-pinene + diphosphate => (2E)-geranyl diphosphate |
| Rhea:RHEA:25491 | 4.2.3.119 | (2E)-geranyl diphosphate <=> (1S,5S)-α-pinene + diphosphate |
| Rhea:RHEA:32892 | 1.14.13.155 | (1S,5S)-α-pinene + NADH + O2 + H+ => α-pinene oxide + NAD+ + H2O |
| Rhea:RHEA:32893 | 1.14.13.155 | α-pinene oxide + NAD+ + H2O => (1S,5S)-α-pinene + NADH + O2 + H+ |
| Rhea:RHEA:32894 | 1.14.13.155 | (1S,5S)-α-pinene + NADH + O2 + H+ <=> α-pinene oxide + NAD+ + H2O |
| BioCyc:RXN-11284 | CPD-461 --> CPD-4892 + PPI | |
| BioCyc:RXN-5106 | 4.2.3.119 | GERANYL-PP --> CPD-4892 + PPI |
| BioCyc:RXN-12972 | 1.14.13.155 | CPD-4892 + NADH + PROTON + OXYGEN-MOLECULE --> ALPHA-PINENE-OXIDE + NAD + WATER |
| Rhea:RHEA:25488 | [25488] (2E)-geranyl diphosphate = (1S,5S)-alpha-pinene + diphosphate | |
| Rhea:RHEA:32891 | [32891] (1S,5S)-alpha-pinene + NADH + O2 + H(+) = alpha-pinene oxide + NAD(+) + H2O |